MATERIAL SAFETY DATA SHEET MSDS 0463 ============================================================================= Section 1 -- PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------- HMIS CODES PRODUCT NAME Health 1 Metacaulk 835+ Flammability 0 Reactivity 0 PRODUCT CODES PPI B 66012, 66019 CHEMICAL FAMILY: Organic/Inorganic USE Firestopping Sealant MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800) 424-9300 Houston, Texas 77055 USA VALIDATION DATE TECHNICAL SERVICE TELEPHONE NO. April 6, 2010 (800) 231-3345 REVISION DATE April 6, 2010 ============================================================================= Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------------------------- % by WT CAS No. INGREDIENT UNITS 3-7 7631-86-9 Amorphous Silica ACGIH TLV N/D ppm OSHA PEL N/D ppm 3-7 22984-54-9 Ketoxime Silane ACGIH TLV N/D ppm OSHA PEL N/D ppm 15-40 1317-65-3 Calcium Carbonate ACGIH TLV 10 mg/m3 OSHA PEL 15 mg/m3 ============================================================================= Section 3 -- HAZARDS IDENTIFICATION ----------------------------------------------------------------------------- SUMMARY OF ACUTE HAZARDS May cause skin irritation. ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Not a respiratory irritant. EYE CONTACT Contact may cause eye irritation. SKIN CONTACT Contact may cause skin irritation. INGESTION Possible irritation to mucous membranes of the mouth, throat, and stomach. SUMMARY OF CHRONIC HAZARDS None known. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Persons with pre-existing skin conditions or chemical allergies may be more susceptible to contact effects of the cured elastomer. ============================================================================= Section 4 -- FIRST AID MEASURES ----------------------------------------------------------------------------- If INHALED: Not a respiratory irritant. If on SKIN: Wash with soap and water. If irritation occurs, seek medical attention. If in EYES: Immediately flush with large amounts of water. If irritation occurs, seek medical attention. If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ============================================================================= Section 5 -- FIRE FIGHTING MEASURES ----------------------------------------------------------------------------- FLASH POINT LEL UEL None N/D N/D EXTINGUSING MEDIA Foam, dry chemical, carbon dioxide or water fog. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (SCBA) and other protective clothing. Hazardous decomposition products possible (see Section 10). UNUSUAL FIRE AND EXPLOSION HAZARDS: Heat may build up and rupture closed containers. ============================================================================= Section 6 -- ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wipe up spills to prevent footing hazard. Avoid flushing into sewers, drains, waterways and soil. Wear protective clothing during clean up. ============================================================================= Section 7 -- HANDLING AND STORAGE ----------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and upright when not in use. To prevent freezing and possible rupture of container, do not store below 40 F. OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues and vapors; treat as if full and observe all product precautions. Do not reuse empty containers. KEEP OUT OF REACH OF CHILDREN. ============================================================================= Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------------------------- RESPIRATORY PROTECTION (SPECIFY TYPE): None required. VENTILATION - LOCAL EXHAUST: Acceptable SPECIAL: N/A MECHANICAL (GENERAL): Preferable OTHER: N/A PROTECTIVE GLOVES: Wear rubber gloves. EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent) OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls recommended. WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse. ============================================================================= Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------------------------- BOILING POINT: 212 F (100 C) @ 760mm Hg SPECIFIC GRAVITY (H20 = 1): 1.3 VAPOR PRESSURE (mm Hg): 17 @ 68 F (20 C) MELTING POINT: N/A VAPOR DENSITY (AIR = 1): N/A EVAPORATION RATE (ETHYL ACETATE = 1): >1 APPEARANCE/ODOR: Gray Paste/Mild Odor SOLUBILITY IN WATER: Soluble VOLATILE ORGANIC COMPOUNDS(VOC)Content (Theoretical Percentage By Weight): <1% or <10 g/L ============================================================================= Section 10 -- STABILITY AND REACTIVITY ----------------------------------------------------------------------------- STABILITY: Stable CONDITIONS TO AVOID: None INCOMPATIBILITY (MATERIALS TO AVOID): None known. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 and fragmented hydrocarbons. HAZARDOUS POLYMERIZATION: Will not occur. ============================================================================= Section 11 -- TOXICOLOGY INFORMATION ----------------------------------------------------------------------------- CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. ----------------------------------------------------------------------------- TOXICOLOGY DATA Ingredient Name ----------------------------------------------------------------------------- Amorphous Silica Oral-Rat LD50: 22,500 mg/kg Inhalation-Rat LC50: N/D Ketoxime Silane Oral-Rat LD50: N/D Inhalation-Rat LC50: N/D Calcium Carbonate Oral-Rat LD50: N/D Inhalation-Rat LC50: N/D ============================================================================= Section 12 -- Ecological Information ----------------------------------------------------------------------------- ECOLOGICAL DATA Ingredient Name ----------------------------------------------------------------------------- Amorphous Silica Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D Ketoxime Silane Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D Calcium Carbonate Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D ============================================================================= Section 13 -- DISPOSAL CONSIDERATIONS ----------------------------------------------------------------------------- Waste Classification: Non-regulated solid waste Disposal Method: Approved landfill Waste from this product is not considered hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in accordance with Federal, State, and Local regulation regarding pollution. ============================================================================= Section 14 -- TRANSPORTATION INFORMATION ----------------------------------------------------------------------------- DOT: Non-Regulated OCEAN (IMDG): Non-Regulated AIR (IATA): Non-Regulated WHMIS (CANADA): Non-Regulated ============================================================================= Section 15 -- REGULATORY INFORMATION ----------------------------------------------------------------------------- REGULATORY DATA Ingredient Name ----------------------------------------------------------------------------- Amorphous Silica SARA 313 N/A TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A Ketoxime Silane SARA 313 N/A TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A Calcium Carbonate SARA 313 N/A TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A ============================================================================= Section 16 -- OTHER INFORMATION ----------------------------------------------------------------------------- This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001